Ooh, how about "Angel" from Massive Attack's album Mezzanine for one of the great album openers? Not only is the menacing mood of this song a great way to kick off the album but the dynamic of the song is so amazing for bringing you into the album. It starts with a simple, sort of mellow, beat and slowly turns into a ferocious monster stalking you from the shadows as you walk to your car in a secluded parking lot late at night.
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