To get a Kurt Cobain-ish sound I'd recommend Electro-Harmonix BigMuff for the fuzzy but not loud parts, Electro-Harmonix Polychorus to get that nice phat chorussy reverb effect he had, DS1 with lots of gain but not too much morph for that distorted tone. He probably had some form of volume limiter for the songs where the volume increase is more subtle.
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