Pink Floyd - Careful With That Axe Eugene (live-ummagumma)
because ive seen at least a dozen people freak out and jump when the scream comes in, and as roger waters said it best "the only thing important about what music is what moves you"
as for emotionally, i usually find random songs that only come up once on alternative radio to be the most powerful, and when i look them up later the feeling is lost, i dont attach myself to songs in that way
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